| S.No | Name | Birth Place | Tenure | Party |
|---|---|---|---|---|
| 1 | Xavier Bettel | Luxembourg, Luxembourg | 4 December 2013 – Incumbent | Democratic Party |
| 2 | Jean-Claude Juncker | Redange, Luxembourg | 20 January 1995 – 4 December 2013 | Christian Social People’s Party |
| 3 | Jacques Santer | Wasserbillig, Luxembourg | 20 July 1984 – 26 January 1995 | Christian Social People’s Party |
| 4 | Pierre Werner | Saint-André-lez-Lille, France | 16 July 1979 – 20 July 1984 | Christian Social People’s Party |
| 5 | Gaston Thorn | Luxembourg, Luxembourg | 15 June 1974 – 16 July 1979 | Democratic Party |
| 6 | Pierre Werner | Saint-André-lez-Lille, France | 2 March 1959 – 15 June 1974 | Christian Social People’s Party |
| 7 | Pierre Frieden | Mertert, Luxembourg | 29 March 1958 – 23 February 1959 | Christian Social People’s Party |
| 8 | Joseph Bech | Diekirch, Luxembourg | 29 September 1953 – 29 March 1958 | Christian Social People’s Party |
| 9 | Pierre Dupong | Heisdorf, Luxembourg | 23 November 1944 – 23 December 1953 | Christian Social People’s Party |
| 10 | Pierre Dupong | Heisdorf, Luxembourg | 5 November 1937 – 23 November 1944 | Party of the Right |
| 11 | Joseph Bech | Diekirch, Luxembourg | 16 July 1926 – 5 November 1937 | Party of the Right |
| 12 | Pierre Prüm | Troisvierges, Luxembourg | 20 March 1925 – 16 July 1926 | Independent National Party |
| 13 | Émile Reuter | Bofferdange, Luxembourg | 28 September 1918 – 20 March 1925 | Party of the Right |
| 14 | Léon Kauffman | Luxembourg, Luxembourg | 18 June 1917 – 28 September, 1918 | Independent |
| 15 | Victor Thorn | Esch-sur-Alzette, Luxembourg | 24 February 1916 – 19 June 1917 | Independent |
| 16 | Hubert Loutsch | Mondercange, Luxembourg | 6 November 1915 – 24 February 1916 | Independent |
| 17 | Mathias Mongenast | Diekirch, Luxembourg | 12 October 1915 – 6 November 1915 | Independent |
| 18 | Paul Eyschen | Diekirch, Luxembourg | 22 September 1888 – 11 October 1915 | Independent |
| 19 | Édouard Thilges | Clervaux, Luxembourg | 20 February 1885 – 22 September 1888 | Independent |
| 20 | Félix de Blochausen | Schieren, Luxembourg | 26 December 1874 – 20 February 1885 | Independent |
| 21 | Emmanuel Servais | Mersch, France | 3 December 1867 – 26 December 1874 | Independent |
| 22 | Victor de Tornaco | Arlon, France | 26 September 1860 – 3 December 1867 | Independent |
| 23 | Charles-Mathias Simons | Bitburg, Prussia | 23 September 1853 – 26 September 1860 | Independent |
| 24 | Jean-Jacques Willmar | Luxembourg, Austrian Netherlands | 6 December 1848 – 23 September 1853 | Independent |
| 29 | G.T.I. de la Fontaine | Luxembourg, Austrian Netherlands | 1 August 1848 – 6 December 1848 | Independent |
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List of Prime Ministers of France
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